[NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3] - Names and Identifiers
Name | Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II)
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Synonyms | (R)-[(RuCl(BINAP))2(μ-Cl)3[NH2Me2] [NH2ME2][(RUCL((R)-BINAP))2(Μ-CL)3] [NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3] -binaphthyl]diruthenate(II),[NH2Me2][{RuCl((R) Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II) Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-2,2μ-bis(diphenylphosphino)-1,1μ-binaphthyl]diruthenate(II) Dimethylammonium dichlorotri(chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(Cl)3] DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-binap)}2(μ-Cl)3]
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CAS | 199684-47-4
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[NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3] - Physico-chemical Properties
Molecular Formula | C90H76Cl5NP4Ru2
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Molar Mass | 1674.89 |
Melting Point | >100°C |
Appearance | Powder |
Color | orange |
Storage Condition | 2-8°C |
Sensitive | air sensitive |
MDL | MFCD09753033 |
[NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3] - Risk and Safety
[NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3] - Introduction
(mu-chloro)bis[(R)-( )-2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II) is an organometallic compound, the chemical formula is[(R)-( )-BDP] -2rucl-2, where BDP represents 2,2 '-bis(diphenylphosphino)-1,1'-binaphthyl.
Nature:
1. Appearance: It is a yellow crystal or powder.
2. Thermal stability: Under inert atmosphere, it can be stable at high temperature.
3. Solubility: soluble in some organic solvents, such as chlorinated hydrocarbons, aromatic hydrocarbons.
Use:
1. Catalyst: dimethyldichlorotribisphosphine ruthenium catalyst has high catalytic activity and selectivity in asymmetric hydrogenation reaction.
2. Synthesis of organic compounds: It can be used to synthesize some chiral organic compounds, such as chiral alcohols and chiral ketones.
Method:
Through dimethyldichloro Tris (μ-chloro) diphenylphosphine diruthenium (II) and (R)-( )-2,2 '-bis (diphenylphosphino)-1,1'-Binaphthyl reaction preparation. The reaction can be carried out under the protection of anhydrous xenon gas at a suitable temperature.
[(R)-( )-BDP]_2RuCl_2 Cl_2Ru(PPh_3)_2 → [(R)-( )-BDP]_2RuCl_2
Safety Information:
The compound has certain toxicity and should follow safe operating procedures when used. Avoid contact with skin and eyes. Appropriate personal protective equipment, such as laboratory gloves and goggles, should be worn when handling the compound.
Last Update:2024-04-10 22:29:15